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- W3144598678 abstract "四面体的压力索引(坐) 被定义在各种各样的硅氧 tetrahedra (SiOT ) 之中描述拓扑的连接在一二进制硅酸盐晶体的离子的簇，眼镜，并且融化。这被发现价值坐很好与拉曼的 thewavenumber 被相关 SiOT 的无横越氧的活跃对称的拉长颤动。当比较分析与价值被做时，亢奋的好结构的 Thespatial 部分尺寸被介绍坐。这能被结束这些概念坐，震动的波浪数字，和空间部分尺寸内在地并且 holographically 被相关并且展出二进制硅酸盐的复杂结构的同形的代表。有不同的碱阳离子的二进制硅酸盐的试验性的拉曼系列被调查。碱阳离子在 SiOT 的 non-bridgingoxygen (NBO ) 的对称的拉长的震动的波浪数字上有小效果，这被表明，但是显著地影响它的拉曼活跃的光生气的节是一致源于 ab initio 计算。二进制硅酸盐的空间部分尺寸被亢奋的好结构主要决定，这能也被结束一离子的簇和很少由碱阳离子影响了，尽管种类一离子的簇和他们的分布被碱氧化物的内容原来分配。并且拉曼当被用于份量上分析时，在高盐基度的孤立的 SiOT 的绝灭的效果应该被考虑的光活动。" @default.
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- W3144598678 date "2006-01-01" @default.
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- W3144598678 title "Raman spectra and structure study of silicate glasses and their liquids" @default.
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