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- W3144776717 abstract "mefenpyrdiethyl (MFD ) 的 photodegradation,除草剂 safener,被在模仿的日光照耀下面使用 Degussa P-25 和 Hombikat UV100 钛氧化物在水的暂停调查。象他们的联合一样的除草剂, pH,催化剂和氢过氧化物剂量的起始的集中的效果被学习并且优化。因此,运动参数被决定,这些过程的有效性被计算率常数估计。假一阶的动力学被观察。在试验性的条件下面,降级率常数强烈用 P-25 被影响,没有显著效果为 Hombikat UV100 被观察。有 B3LYP/6-311+G 的 DFT 计算( 2d , p )// B3LYP/6-31+G ( d , p )理论的水平被执行当 MFD 底层的费用状态变化时,检查重要 conformational 变化是否发生并且这些变化是否能在学习 pH 上在 photodegradation 率常数的相关性起一个作用。高分辨率团 spectrometry (FT-ICR/MS ) 被实现识别主要降级产品。" @default.
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- W3144776717 date "2012-01-01" @default.
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- W3144776717 title "Efficiency and degradation products elucidation of the photodegradation of mefenpyrdiethyl in water interface using TiO2 P-25 and Hombikat UV100" @default.
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