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- W3145308782 abstract "Polystyrene/iron-nickel (PS/FeNi3) nanocomposites were synthesized via an in-situ polymerization route and characterized by XRD,SEM and FTIR. FeNi3 nanoparticles were characterized by TEM and XRD. The pure FeNi3 nanoparticles (100～125 nm) were highly clustered and percolated through the PS matrix. When the content of FeNi3 nanoparticles reached 5 wt%,an interaction between FeNi3 nanoparticles and PS matrix was observed. The thermal decomposition behavior of PS/FeNi3 nanocomposites was investigated by thermal analysis. The activation energies (E) and pre-exponential factors (lnA) were calculated by using Archar method. The results show that the thermal decomposition of pure PS is a one-dimensional diffusion mechanism. A three-dimensional diffusion mechanism appears when FeNi3 nanoparticles incorporate. The E of PS/FeNi3 nanocomposites with different FeNi3 contents is 217.5,225.3,180.6 and 73.0 kJ·mol-1,and the corresponding lnA is 35.6,34.9,27.5 and 10.4 S-1,respectively." @default.
- W3145308782 created "2021-04-13" @default.
- W3145308782 creator A5015266991 @default.
- W3145308782 date "2010-01-01" @default.
- W3145308782 modified "2023-09-25" @default.
- W3145308782 title "Characterization and Non-isothermal Decomposition Kinetic Analysis of PS/FeNi_3 Nanocomposites" @default.
- W3145308782 hasPublicationYear "2010" @default.
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