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- W3145339944 abstract "The oxidation of formaldehyde in alkaline solution was studied by in situ rapid-scan time-resolved IR spectroelectrochemistry（RS-TR-FTIRS） method.In the potential range between -0.7 V and 0.2 V,the gem-diol anions were oxidized(according to the 2765 cm-1 of-νH-O and 1034 cm-1 ofνco downward IR bands) and the formate ions appeared(according to the 1588,1357 cm-1 of the asymmetric and symmetricνoco and 1380 cm-1 ofδC-H upward IR bands) in aqueous solution.It was also confirmed that gem-diol anion was oxidized(according to the 2026,1034 cm-1 downward IR bands) to formate ions (according to the 1595,1357,1380 cm-1 upward IR bands) and water(according to the 3427 cm-1 ofνH- O upward IR band) in heavy water solution.The results illustrated that formaldehyde formed gem-diol anion in alkaline solution and was absorbed on the electrode surface;then gem-diol anion was oxidized to formate ions and water." @default.
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- W3145339944 date "2013-01-01" @default.
- W3145339944 modified "2023-09-23" @default.
- W3145339944 title "Study of the electrochemical oxidation mechanism of formaldehyde on gold electrode in alkaline solution" @default.
- W3145339944 hasPublicationYear "2013" @default.
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