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- W3145510228 endingPage "115173" @default.
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- W3145510228 abstract "Discriminating the electrochemiluminescence (ECL) of differed luminophores is crucial for ECL multiplexing. However, because of the limited potential window for ECL assay and the overlapped triggering-potential-range between different luminophores, the potential-resolved ECL multiplexing with good resolutions (Rs) is still a great challenge. Herein, a single anodic ECL from two luminophores in the aqueous solution was discriminated completely (baseline separation, Rs ≥ 1.5) in a potential-resolved way with the water-soluble CuInS2@ZnS ([email protected]) nanocrystals (NCs) and [Ru(bpy)2(dcbpy)]2+ as luminophores and N2H4 as the co-reactant. N2H4 could be electrochemically oxidized to reducing radicals and then reacted with the electrochemically oxidized [email protected] NCs and [Ru(bpy)2(dcbpy)]2+ in sequence to produce co-reactant ECL. The potential-resolved ECL of [email protected] NCs/N2H4 and [Ru(bpy)2(dcbpy)]2+/N2H4 could be well defined and distinguished from each other upon potential scanning (Rs = 2.60) and utilized for simultaneously determining human prostate specific antigen and carcinoma antigen 125 at the pathological cut-off concentration (Rs = 1.56)." @default.
- W3145510228 created "2021-04-13" @default.
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- W3145510228 date "2021-05-01" @default.
- W3145510228 modified "2023-10-16" @default.
- W3145510228 title "Highly potential-resolved anodic electrochemiluminescence multiplexing immunoassay with CuInS2@ZnS nanocrystals and [Ru(bpy)2(dcbpy)]2+ as emitters" @default.
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- W3145510228 doi "https://doi.org/10.1016/j.jelechem.2021.115173" @default.
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