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- W3145635612 abstract "Lead vanadateglassesofthesystem5Li2O(45x) PbO(50+x) V2O5, with x ¼ 0, 5,10,and15mol% havebeenpreparedandstudiedbydifferentialscanningcalorimetry(DSC).Thecrystallizationkinetics of theglasseswereinvestigatedundernon-isothermalconditionsapplyingtheformaltheoryof transformations forheterogeneousnucleationtotheexperimentaldataobtainedbyDSCusing continuous-heatingtechniques.Inaddition,fromdependenceoftheglass-transitiontemperature(Tg) on theheatingrate,theactivationenergyfortheglasstransitionwasderived.Similarlytheactivation energy ofthecrystallizationprocesswasdeterminedandthecrystallizationmechanismwas characterized. Theresultsrevealtheincreaseoftheactivationenergyforglasstransitionwhichwas attributedtotheincreaseintherigidity,thecross-linkdensityandthepackingdensityoftheseglasses. The phasesintowhichtheglasscrystallizeshavebeenidentifiedbyX-raydiffraction.Diffractogramsof the transformedmaterialindicatethepresenceofmicrocrystallitesofLi0.30V2O5, Li0.67O5V2, LiV6O15, Li4O4Pb,andO7Pb2V2 in aremainingamorphousmatrix." @default.
- W3145635612 created "2021-04-13" @default.
- W3145635612 creator A5065999879 @default.
- W3145635612 date "2009-01-01" @default.
- W3145635612 modified "2023-09-27" @default.
- W3145635612 title "CrystallizationkineticsofLi2O–PbO–V2O5 glasses" @default.
- W3145635612 hasPublicationYear "2009" @default.
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