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- W3145768781 abstract "五新光学地活跃的聚酰胺(舞步) 6a 鈥? e 被2-( 1,3-isoindolinedione-2-yl )的直接 polycondensation 反应准备作为有在 triphenyl 亚磷酸盐( TPP )的中等在于的各种各样的芳香的肼 5a 鈥? e 的新 chiral 二酸的 -glutaric 酸 4 ，钙氯化物， pyridine ( Py )和 N-methyl-2-pyrrolidone ( NMP )。polycondensation 反应与 0.26 鈥 ?.39 dL/g 的固有的粘性在量的收益生产了一系列 polyamids 6a 鈥 ? e。产生聚合物充分借助于 1H-NMR，英尺红外光谱学，元素的分析，固有的粘性和特定的旋转被描绘。这些聚合物的热性质用热 gravimetric 分析(TGA ) 和微分热 gravimetry (DTG ) 被调查。在聚合物的一个笨重的悬挂的组锁住的 Phthalimide 戒指扰乱 interchain 和 intrachain 相互作用并且使这些成为在容易地可溶的舞步极， aprotic 溶剂象 N 那样， N-dimethyl 乙酰胺( DMAc )， N ， N-dimethyl formamide ( DMF )， dimethyl sulfoxide ( DMSO )， N-methyl-2-pyrrolidone ( NMP )和硫磺的酸。关键词聚酰胺 - 光学地活跃的聚合物 - 热地稳定的聚合物" @default.
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- W3145768781 date "2010-01-01" @default.
- W3145768781 modified "2023-09-28" @default.
- W3145768781 title "SYNTHESIS AND CHARACTERIZATION OF OPTICALLY ACTIVE POLYAMIDES BASED ON 2-（1,3-ISOINDOLINEDIONE-2-YL）GLUTARIC ACID BY DIRECT POLYCONDENSATION" @default.
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