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- W3145809953 abstract "A new sodium indium phosphate Na6In4 [P7O24 (OH)5]•4H2O was synthesized under a mild hydrothermal condition and its structure was determined by means of single-crystal X-ray diffraction methods. The title compound crystallizes in a hexagonal system, space group P63, with a=0.95023(5)nm, b=0.95023(5)nm, c=1.6942(2)nm, α=90°, β=90°, γ=120°, V=1.3248(2)nm^3, Z=8, structure refined to R=0.0528 and wR=0.1165 for 2134 independent observed reflections. The three-dimensional network structure consists of helical chains formed by apex-sharing polyhedra. The connection of the chains results in 4-and 8-polyhedral rings and cages centered by three indium metal connecting oxygen atoms formed by three 4-rings. The three-connected oxygen atom is firstly observed in indium phosphate systems." @default.
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- W3145809953 date "2004-10-10" @default.
- W3145809953 modified "2023-09-24" @default.
- W3145809953 title "Na6In4[P7O24（OH）5]·4H2O的水热合成与表征" @default.
- W3145809953 hasPublicationYear "2004" @default.
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