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- W3145990247 abstract "酯化作用或 transesterification 反应通常面对同类或异构的催化剂被执行。然而，最近，一个新方法被 tributyl 硼酸盐在没有溶剂、没有催化剂的条件下面为羧基的酸的酯化作用报导。为了在酯化作用反应显示出 trialkyl 硼酸盐酉旨的合成能力，这里，由在一样的条件下面的 tributyl- ， triisoamyl- ，和 tribenzyl 硼酸盐的另外的羧基的酸和二酸的酯化作用被报导。一些准备酉旨和 diester 产品作为可塑剂和合成酉旨底润滑剂发现了宽应用。酯化作用反应利落地在没有催化剂的条件下面当任何溶剂不在时被执行了。最大的率属于在大约 6.5 h 以内到达了大约 76% 的 isoamyl trichloroacetate (VIb ) 。根据获得的调查结果，看起来，羧基的酸上的电子撤退组便于酯化作用反应。" @default.
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- W3145990247 date "2007-01-01" @default.
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- W3145990247 title "Esterification of Carboxylic Acids and Diacids by Trialkyl Borate under Solvent- and Catalyst-Free Conditions" @default.
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