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• W3146025862 endingPage "477" @default.
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• W3146025862 abstract "The structural, magnetic, and nonstoichiometric properties of the perovskite-like Pr1−xSrxCoO3−δ phase (0≤x≤0.80) have been studied by powder X-ray and neutron diffraction and magnetic susceptibility measurements between 5 and 295 K as well as by redox titration. In the compostion range 0≤x≤0.30 the structure can be described with a GdFeO3-type atomic arrangement (space group Pnma), while the structure in the composition range 0.30<x≤0.80 involves a lower symmetry (space group P21/n). Samples with 0.10≤x≤0.80 exhibit ferromagnetism below a Curie temperature of ≤250 K, depending on the composition. The Pr1−xSrxCoO3−δ phase behaves as a relatively hard magnetic material. For samples prepared and cooled to room temperature in air, the oxidation state of cobalt increases linearly up to x≈0.50 and stabilizes at +3.4 for higher substitution levels of Sr. On the basis of the present data, it is not possible to prove or disprove that there occurs charge ordering in Pr1−xSrxCoO3−δ." @default.
• W3146025862 created "2021-04-13" @default.
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• W3146025862 date "1999-11-01" @default.
• W3146025862 modified "2023-10-18" @default.
• W3146025862 title "Structure and Magnetism of Pr1−xSrxCoO3−δ" @default.
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• W3146025862 doi "https://doi.org/10.1006/jssc.1999.8384" @default.
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