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- W3146029856 abstract "为到液体(GTL ) 的直接气体,为甲烷 dehydroaromatization 生产精力来源的一个新奇过程被需要。在 H-MFI 沸石上支持 MoO3 在一个固定的床反应堆在 973 K 为甲烷的 dehydroaromatization 显示出高催化的能力和一项选择活动到苯。在另一方面,由在所有催化剂的活跃地点上的焦炭的释放在反应期间被形成。H2 共同喂压制了释放,它可能由于在 coking 的减少数量。瞬间小锚 X 光检查吸收罚款结构(XAFS ) 结果在 dehydroaromatization 以后与低 crystallinity 显示出驱散的 Mo2C 种类的形成。瞬间 LIII 边 XANES (X 光检查吸收近边的结构) 包括 Mo2C 和 Mo-oxycarbide (MoOxCy ) 显示了活跃瞬间种类的形成,在氧化还原作用状态应该当 H2 不在时是独立的的地方。Mo-oxycarbide 种类充当高度活跃的种类,这被结束,并且他们的稳定性面对 H2 影响了持久的活动。" @default.
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- W3146029856 date "2009-01-01" @default.
- W3146029856 modified "2023-09-23" @default.
- W3146029856 title "Methane dehydroaromatization over Mo-modified H-MFI for gas to liquid catalysts" @default.
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