Matches in SemOpenAlex for { <https://semopenalex.org/work/W3146151010> ?p ?o ?g. }
- W3146151010 endingPage "213799" @default.
- W3146151010 startingPage "213799" @default.
- W3146151010 abstract "Transition-metal hydride complexes are plenteous in organometallic chemistry. The reactivity of metal hydrides is determined by three possible pathways of M–H bond cleavage: homolytic cleavage yielding a hydrogen radical (H), and heterolytic cleavage generating either a proton (H+) or hydride (H−). These steps, especially the proton and hydride transfer, are critical in a vast array of stoichiometric and catalytic transformations. Many late transition metal hydrides are supported by phosphine ligands, which allow tuning the electronic and steric properties at a metal center in a systematic and predictable way. In this non-exhaustive review we attempt to trace the influence of phosphines properties on the reactivity of transition metal hydrides in topical stoichiometric and catalytic processes highlighting the reactions’ mechanisms and the role of hydrogen bonding interactions in the intermediates of hydrogen transfer reactions." @default.
- W3146151010 created "2021-04-13" @default.
- W3146151010 creator A5004284214 @default.
- W3146151010 creator A5012399577 @default.
- W3146151010 creator A5016848542 @default.
- W3146151010 creator A5027884354 @default.
- W3146151010 creator A5046678827 @default.
- W3146151010 creator A5077538926 @default.
- W3146151010 date "2021-07-01" @default.
- W3146151010 modified "2023-10-01" @default.
- W3146151010 title "Influence of phosphine (pincer) ligands on the transition metal hydrides reactivity" @default.
- W3146151010 cites W109955049 @default.
- W3146151010 cites W1566324729 @default.
- W3146151010 cites W166111284 @default.
- W3146151010 cites W1964905221 @default.
- W3146151010 cites W1965577187 @default.
- W3146151010 cites W1965587829 @default.
- W3146151010 cites W1965691278 @default.
- W3146151010 cites W1967802688 @default.
- W3146151010 cites W1968168327 @default.
- W3146151010 cites W1974289997 @default.
- W3146151010 cites W1978008449 @default.
- W3146151010 cites W1979007101 @default.
- W3146151010 cites W1980225533 @default.
- W3146151010 cites W1980641144 @default.
- W3146151010 cites W1980901019 @default.
- W3146151010 cites W1985037036 @default.
- W3146151010 cites W1990108593 @default.
- W3146151010 cites W1991653595 @default.
- W3146151010 cites W1991933241 @default.
- W3146151010 cites W1993853667 @default.
- W3146151010 cites W1995991942 @default.
- W3146151010 cites W1996610836 @default.
- W3146151010 cites W1997119539 @default.
- W3146151010 cites W1997167145 @default.
- W3146151010 cites W1997405879 @default.
- W3146151010 cites W1998903130 @default.
- W3146151010 cites W2002262128 @default.
- W3146151010 cites W2003129104 @default.
- W3146151010 cites W2004319596 @default.
- W3146151010 cites W2005853185 @default.
- W3146151010 cites W2006355795 @default.
- W3146151010 cites W2008613863 @default.
- W3146151010 cites W2009626516 @default.
- W3146151010 cites W2011042434 @default.
- W3146151010 cites W2011827543 @default.
- W3146151010 cites W2012023595 @default.
- W3146151010 cites W2016452536 @default.
- W3146151010 cites W2018593309 @default.
- W3146151010 cites W2018626355 @default.
- W3146151010 cites W2019589177 @default.
- W3146151010 cites W2020078456 @default.
- W3146151010 cites W2020561818 @default.
- W3146151010 cites W2022315303 @default.
- W3146151010 cites W2023310547 @default.
- W3146151010 cites W2023698367 @default.
- W3146151010 cites W2030674590 @default.
- W3146151010 cites W2032142610 @default.
- W3146151010 cites W2032294243 @default.
- W3146151010 cites W2033288172 @default.
- W3146151010 cites W2036885659 @default.
- W3146151010 cites W2037907398 @default.
- W3146151010 cites W2038071113 @default.
- W3146151010 cites W2042267313 @default.
- W3146151010 cites W2042926180 @default.
- W3146151010 cites W2043729794 @default.
- W3146151010 cites W2047492063 @default.
- W3146151010 cites W2050592102 @default.
- W3146151010 cites W2050979151 @default.
- W3146151010 cites W2055069218 @default.
- W3146151010 cites W2057300170 @default.
- W3146151010 cites W2059530247 @default.
- W3146151010 cites W2060157763 @default.
- W3146151010 cites W2062927193 @default.
- W3146151010 cites W2063101113 @default.
- W3146151010 cites W2064385879 @default.
- W3146151010 cites W2064761491 @default.
- W3146151010 cites W2068275679 @default.
- W3146151010 cites W2068414921 @default.
- W3146151010 cites W2074286899 @default.
- W3146151010 cites W2080649263 @default.
- W3146151010 cites W2081890623 @default.
- W3146151010 cites W2082596177 @default.
- W3146151010 cites W2084382718 @default.
- W3146151010 cites W2084863239 @default.
- W3146151010 cites W2088980727 @default.
- W3146151010 cites W2089655596 @default.
- W3146151010 cites W2090589056 @default.
- W3146151010 cites W2090604189 @default.
- W3146151010 cites W2093177017 @default.
- W3146151010 cites W2095014431 @default.
- W3146151010 cites W2095417590 @default.
- W3146151010 cites W2096627864 @default.
- W3146151010 cites W2098893309 @default.
- W3146151010 cites W2105784082 @default.
- W3146151010 cites W2111503687 @default.
- W3146151010 cites W2111894677 @default.
- W3146151010 cites W2114633523 @default.