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- W3146291485 abstract "A novel mercury(n)complex HgL_2Br_2 was prepared from HgBr_2 and the organic ligand 2-(N-methyl-N-(4-((E)-2-(pyridine-4-yl)vinyl)phenyl)amino)ethanol(L).The ligand was synthesized and then characterized by FT-IR spectroscopy,~1H NMR,mass spectrum and elemental analysis,while the single-crystal diffraction data of the complex were collected on a Siemens Smart CCD diffractometer.The complex crystallizes in triclinic space group P_1~-with a=5.367(5),b= 12.466(5),c=23.945(5)(?),α=90.812(5),β=96.318(4),γ=96.093(5)°,Z=2,D_c=1.817g·cm~(-3),μ=7.395 mm~(-1),S=0.825,and the final R=0.0396.The Hg(Ⅱ)ion in the distorted tetrahedral mercury(Ⅱ)complex C_(32)H_(36)HgBr_2N_4O_2 is coordinated by two N atoms from the two ligands together with two bromide ions.Solid-state emission of the ligand and its complex has been investigated at room temperature." @default.
- W3146291485 created "2021-04-13" @default.
- W3146291485 creator A5005865870 @default.
- W3146291485 date "2010-01-01" @default.
- W3146291485 modified "2023-09-25" @default.
- W3146291485 title "Studies on the Crystal Structure and Photoluminescence of a Mercury(II) Complex Based on a Novel Pyridine Ligand" @default.
- W3146291485 hasPublicationYear "2010" @default.
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