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• W3146439362 abstract "Hemitheion (1), a new sulfur-containing vobasane-type indole alkaloid, was isolated, together with three known compounds, vobasine (2), gelsedine (3), and gelsemicine (4), from the alkaloid extract of the stems of Mostuea brunonis Didr. (Gelsemiaceae). Compound 1 could be straightforwardly isolated. Its structure was elucidated by a combination of spectroscopic methods. Besides corresponding to a formerly postulated biosynthetic intermediate toward theionbrunonines, hemitheion (1) stands among the few monomeric vobasanes lacking an oxygen at C-3. Hemitheion (1) showed moderate antiplasmodial activity in the micromolar range against the strain FcB1 of Plasmodium falciparum and no cytotoxic activity against the MRC-5 cell line at 20 μM." @default.
• W3146439362 created "2021-04-13" @default.
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• W3146439362 date "2021-04-07" @default.
• W3146439362 modified "2023-10-16" @default.
• W3146439362 title "Targeted Isolation of Hemitheion from <i>Mostuea</i> <i>brunonis</i>, a Proposed Biosynthetic Intermediate of Theionbrunonines" @default.
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• W3146439362 doi "https://doi.org/10.1021/acs.jnatprod.1c00143" @default.
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