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- W3146587911 abstract "A new d10 transition-metal iodate fluoride, namely, Cd3(IO3)(IO4)F2·0.1CdO, was successfully designed and synthesized via the mid-infrared hydrothermal method. It crystallizes in the polar space group R3m and features the coexistence of the [IO3]− and [IO4]3– groups. Cd3(IO3)(IO4)F2·0.1CdO has a strong second-harmonic-generation response of about 3.0 times that of KDP(KH2PO4), large birefringence (0.133 at 546.1 nm), and a wide energy band gap (4.00 eV). In addition, the power laser damage threshold (LDT) measurement indicated that it possesses a high LDT of 84.29 MW/cm2, which is about 30 times that of AgGaS2. These superior properties showed that Cd3(IO3)(IO4)F2·0.1CdO may be an excellent nonlinear-optical crystal for visible and mid-infrared application." @default.
- W3146587911 created "2021-04-13" @default.
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- W3146587911 date "2021-04-06" @default.
- W3146587911 modified "2023-10-14" @default.
- W3146587911 title "Cd<sub>3</sub>(IO<sub>3</sub>)(IO<sub>4</sub>)F<sub>2</sub>·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO<sub>3</sub>]<sup>−</sup> and [IO<sub>4</sub>]<sup>3–</sup> Groups" @default.
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- W3146587911 doi "https://doi.org/10.1021/acs.inorgchem.1c00506" @default.
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