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- W3146670653 abstract "The first Cu-catalyzed asymmetric borylative cyclization of cyclohexadienone-containing 1,6-enynes is achieved through a tandem process: selective β-borylation of propargylic ether and subsequent conjugate addition to cyclohexadienone. The reaction proceeds with excellent regioselectivity and enantioselectivity to afford an optically pure cis-hydrobenzofuran framework bearing alkenylboronate and enone substructures. Furthermore, the resulting bicyclic products could be converted to bridged and tricyclic ring structures. This method extends the realm of Cu-catalyzed asymmetric tandem reactions using bis(pinacolato)diboron (B2pin2)." @default.
- W3146670653 created "2021-04-13" @default.
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- W3146670653 date "2013-07-30" @default.
- W3146670653 modified "2023-10-11" @default.
- W3146670653 title "Cu-Catalyzed Asymmetric Borylative Cyclization of Cyclohexadienone-Containing 1,6-Enynes" @default.
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- W3146670653 doi "https://doi.org/10.1021/ja404593c" @default.
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