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- W3146820405 abstract "The Mn spin correlations were studied near the ${O}^{ensuremath{'}}$-$O$ phase transition at ${T}_{text{JT}}=750$ K up to 950 K with ${}^{17}mathrm{O}$ and ${}^{139}mathrm{La}$ NMR in a stoichiometric ${mathrm{LaMnO}}_{3}$ crystalline sample. The measured local hyperfine fields originate from the electron density transferred from the ${e}_{g}^{}$ and ${t}_{2g}^{}$ orbitals to the 2$s$(O) and 6$s$(La) orbits, respectively. By probing the oxygen nuclei, we show that the correlations of the Mn spins are ferromagnetic in the $mathit{ab}$ plane and robust up to ${T}_{text{JT}}$, whereas along the $c$ axis they are antiferromagnetic and start to melt below ${T}_{text{JT}}$, at about 550 K. Above ${T}_{text{JT}}$, the ferromagnetic Mn-Mn exchange interaction is found isotropic. The room-temperature orbital mixing angle, ${ensuremath{varphi}}_{mathrm{NMR}}=109ifmmodepmelsetextpmfi{}1.5{}^{ensuremath{circ}}$, of the ${e}_{g}^{}$ ground state is close to the reported value which was deduced from structural data on Jahn-Teller distorted ${mathrm{MnO}}_{6}$ octahedra. For $T>{T}_{text{JT}}$, ${mathrm{LaMnO}}_{3}$ can be described in terms of nonpolarized ${e}_{g}$ orbitals since both ${e}_{g}$ orbitals are equally occupied." @default.
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- W3146820405 date "2013-03-26" @default.
- W3146820405 modified "2023-10-17" @default.
- W3146820405 title "Melting of the orbital order in LaMnO<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>3</mml:mn></mml:msub></mml:math>probed by NMR" @default.
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- W3146820405 doi "https://doi.org/10.1103/physrevb.87.125142" @default.
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