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- W3147281784 abstract "乙烯 trithiocarbonate 与 dimethyl acetylenedicarboxylate 反应了供应 tetramethyl thiopyran-4-spiro-2-(1,3-dithiolane )-2,3,5,6-tetracarboxylate, 新 thiopyran-4-spiro-2-(1,3-dithiolane ) 杂环的化合物，和主要产品 dimethyl 2-thioxo-1,3-dithiole-4,5-dicarboxylate 的次要的产品。新 heterocycle 可能被形成通过一[2 + 2 ] 在乙烯 trithiocarbonate 和 dimethyl acetylenedicarboxylate 之间的 cycloaddition 由 1,3-dipolar cycloaddition 列在后面或[4 + 2 ] cycloaddition。新混合物的水晶结构表明 thiopyran 戒指和 1,3-dithiolane 一半对对方垂直。" @default.
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- W3147281784 date "2011-01-01" @default.
- W3147281784 modified "2023-09-24" @default.
- W3147281784 title "New thiopyran-4-spiro-2′-（1,3-dithiolane）：Formation mechanism and crystal structure" @default.
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