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- W3147346460 abstract "在 pH 4.26.0 HAc-NaAc 缓冲区媒介，散布分开的基本三苯代甲烷的紧张的回声瑞利染，例如甲基紫( MV )，乙醇紫( EV )，水晶紫( CV )，甲基绿色( MeG )，碘绿色( IG )，孔雀石绿色( MG )，轻绿色( LG )，和钨酸盐离子答案，是很弱的，但是当这些 cationic 染时，与钨酸盐离子反应( WO4 2 ?)形成离子协会建筑群，他们的 RRS 严厉地被提高，新 RRS 系列出现。甲基的反应产品紫，乙醇紫，并且与 WO4 2 紫的水晶？类似光谱特征并且在 330 nm 和 560 nm 有二座强壮的 RRS 山峰。甲基绿色的反应产品，碘绿色，孔雀石绿色，有 WO4 2 的轻绿色？类似光谱特征并且在大约 335 nm， 450 nm 和 580 nm 有三座 RRS 山峰。七种反应产品的敏感显示出孔雀石绿色的一个序列 > 轻绿色 > 水晶紫 > 乙醇紫 > 甲基绿色 > 碘绿色 > 甲基紫。线性范围和上述七个系统的察觉限制是 0.062.78 g mL ? 1 和 18.1 ng mL ? 1 ( MG )， 0.084.83 g mL ? 1 和 22.6 ng mL ? 1 ( BG )， 0.104.90 g mL ? 1 和 31.4 ng mL ? 1 ( CV )， 0.142.95 g mL ? 1 和 40.5 ng mL ? 1 ( EV )， 0.173.70 g mL ? 1 和 50.2 ng mL ? 1 ( MeG )， 0.225.70 g mL ? 1 和 67.1 ng mL ? 1 ( IG )，并且 0.257.30 g mL ? 1 和 76.3 ng mL ? 1 ( MV )。为把钨酸盐离子用作探查的基本三苯代甲烷染料的决心的一个敏感、简单、快的 RRS 方法被开发了。方法对在鱼肉的孔雀石绿色残余的决心适用。" @default.
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- W3147346460 date "2010-01-01" @default.
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- W3147346460 title "Tungstate ion resonance Rayleigh scattering method for determination of basic triphenylmethane dyes" @default.
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