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- W3147347100 abstract "Sodium and potassium are considered to be the most promising anode candidates due to their easy availability, low-cost and similar chemical properties to lithium. Here, novel 3D accordion-like fluorinated graphite nanosheets (FGNSs) are reported as cathodes for sodium primary batteries (SPBs) and potassium primary batteries (PPBs). The FGNSs-x cathode exhibits unprecedented power and energy density due to the impressive 3D structure, high F/C ratio (1.0), and more surface CC bonds (7.14%). The FGNSs-1.0 exhibits very high specific capacities of 831.3 and 834.1 mAh g-1 for SPBs and PPBs, respectively, close to the theoretical capacity. Besides, the maximum energy density of FGNSs-1.0 in SPBs and PPBs are 1960.5 and 2144.6 Wh kg-1 , respectively. The maximum power density for Na/CFx and K/CFx batteries could reach up to 7076.8 and 6227.4 W kg-1 , respectively. The electrochemical performance of FGNSs-1.0 at extreme temperatures (-30 to 100 °C), long storage time (60 days), high mass loading (3.6 mg cm-2 ), and pouch-type cell is also evaluated for the first time. Surprisingly, FGNSs-1.0 has outstanding performance in these projects. Therefore, the new-type Na/CFx and K/CFx primary battery systems developed here have broad application prospects in high-energy applications that require high-power, low-cost, and normal use under extreme conditions." @default.
- W3147347100 created "2021-04-13" @default.
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- W3147347100 date "2021-04-10" @default.
- W3147347100 modified "2023-10-09" @default.
- W3147347100 title "Accordion‐Like Fluorinated Graphite Nanosheets with High Power and Energy Densities for Wide‐Temperature, Long Shelf‐Life Sodium/Potassium Primary Batteries" @default.
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- W3147347100 doi "https://doi.org/10.1002/smll.202008163" @default.
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