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- W3147465280 abstract "Carbon-encapsulated cobalt and nickel nanoparticles with core/shell structure have been successfully synthesized with maize-derived starch as carbon source and metal nitrate as metal precursors in flowing hydrogen. The as-prepared M@Cs materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction technique (XRD) and vibrating sample magnetometer (VSM). The effects of the metal precursors on the structure and the size of the M@Cs materials were investigated, and the magnetic properties of the M@Cs materials were measured. The results show that the structure and the size of the M@Cs materials are different in terms of the different metal precursors. The Co@Cs materials are made of the fcc-Co core and the graphitic carbon shell, of which the core diameter is in a range of 20–35nm, while the Ni@Cs materials are composed of fcc-Ni core and the amorphous carbon shell, of which the core diameter ranges from 30 to 50nm. The hysteresis loops of the as-made M@Cs materials show that some of the nanoparticles are in a superparamagnetic state at room temperature. A mechanism is proposed to explain the growth process of the M@Cs materials. It is believed that the starch with the helical structure is responsible for the formation of the M@Cs materials featuring the core/shell structure. © 2008 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved." @default.
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- W3147465280 date "2008-01-01" @default.
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- W3147465280 title "reparation and magnetic behavior of carbon-encapsulated obalt and nickel nanoparticles from starch" @default.
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