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• W3147535210 abstract "We report on the synthesis of PTTA that is a product of polymeric condensation of triquinoyl with 1,2,4,5-tetraaminobenzene and on the application of this polymer as the redox-active material for an electrode in lithium-ion batteries. Two electrolytes were selected: 1 M LiPF6 in ethylene carbonate : dimethyl carbonate mixture (1 : 1) and the same electrolyte with the additive of benzo-15-crown-5 (5 wt%). The new organic electrode has a theoretical capacity of 344 mAh g−1 (3e−), and its redox processes have been investigated using CV, charge-discharge cycling, and quantum-chemical modeling. It was shown that added benzo-15-crown-5 allows achieving the theoretical discharge capacity under the same conditions. Quantum chemical DFT modeling provided insights into the mechanistic aspects of PTTA metallation." @default.
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• W3147535210 date "2021-05-01" @default.
• W3147535210 modified "2023-09-29" @default.
• W3147535210 title "Synthesis and investigation of a new organic electrode material based on condensation product of triquinoyl with 1,2,4,5-tetraaminobenzene" @default.
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• W3147535210 doi "https://doi.org/10.1016/j.jelechem.2021.115234" @default.
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