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- W314760193 abstract "Carbide molecules are studied thoroughly by means of high-temperature mass spectroscopy. A summary list is presented of molecules that have been identified. It can be seen that molecules of the type MeC/sub 2/ and MeC are the most characteristic for the majority of the elements. The dissociation energies of the MeC/sub 2/ and MeO molecules correlate quite well and the authors obtain a correlation equation from them. The hypothetical mechanism of carbothermal reduction is examined and it is shown that in order for a process of carbothermal reduction limited by the rate of withdrawal of reaction products from the oxide surface to be steady-state, it is necessary that the partial pressure of the carbide molecules be commensurate with the partial pressure of the metal atoms. The nonequilibrium content of carbon in the gas phase and the source of nonequilibrium content of carbon vapor are investigated." @default.
- W314760193 created "2016-06-24" @default.
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- W314760193 date "1985-04-01" @default.
- W314760193 modified "2023-09-26" @default.
- W314760193 title "Role of free carbon in gas phase in carbothermal reduction of oxides in graphite furnaces for atomi c absorption analysis" @default.
- W314760193 hasPublicationYear "1985" @default.
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