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- W3147659825 abstract "Cyclic voltammetric and chronoamperometric techniques were employed to study the temperature effects on the electrochemical reaction of Fe(CN)63-/4-by self-made thermostatic water bath electrochemical cell.The diffusion coefficient D and the formal heterogeneous electron-transfer rate constant k0 were calculated at different temperatures from 25 ℃ to 75 ℃.In the Fe(CN)63-/4-system,the DO values of Fe(CN)63-were directly proportional to temperature,while DR of Fe(CN)64-inversely proportional to temperature.The values of k0 decreased with the increase of temperature due possibly to the electrode passivation resulted from the decomposition of Fe(CN)63-/4-to a Prussian blue like film.Since the core of Cytochrome c is the heme iron porphyrin,the redox of Cytochrome c reflects that of the iron atoms,which is,in certain degrees,similar to the electrochemical reactions of Fe(CN)63-/4-system.Accordingly,the same techniques were used to study the temperature effects on Cytochrome c.The kinetic parameters of Cytochrome c at different temperatures were also calculated and compared with those of Fe(CN)63-/4-system." @default.
- W3147659825 created "2021-04-13" @default.
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- W3147659825 date "2012-01-01" @default.
- W3147659825 modified "2023-09-24" @default.
- W3147659825 title "Temperature Effects on the Electron-Transfer Reactions of Fe(CN)_6~(3-/4-) and Cytochrome c" @default.
- W3147659825 hasPublicationYear "2012" @default.
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