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• W3148153237 startingPage "9213" @default.
• W3148153237 abstract "Two unprecedented and stable metal–organic frameworks, {[Co2(H2O)2(L)(OH)]·2.5H2O·0.5DMF}n (1) and {[Ni2(H2O)2(L)(OH)]·1.75H2O}n (2), have been synthesized (H3L = 5-(5-carboxy-pyridin-3-yloxy)-isophthalic acid, DMF = N,N-dimethylformamide). Structural analysis shows that 1 and 2 are heteronuclear isomorphous, possessing a three-dimensional (3D) (4,8)-connected flu/fluorite topological framework formed through the interconnection of tetranuclear butterfly {M4(COO)6(OH)2} clusters and the ligands. Although the frameworks of these two compounds are similar, their magnetic properties are different. Compound 1 exhibits an antiferromagnetic interaction in the high-temperature region, while 2 shows a weak ferromagnetic interaction in the whole-temperature region. Furthermore, considering the presence of hydroxyl groups and water molecules in the frameworks, we tested their proton conductivity. The efficient proton transfer pathway in the framework endowed 1 and 2 with excellent proton conductivities of 9.07 × 10–5 and 1.29 × 10–4 S·cm–1 at 363 K and 98% relative humidity (RH), respectively." @default.
• W3148153237 created "2021-04-13" @default.
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• W3148153237 date "2021-03-26" @default.
• W3148153237 modified "2023-10-01" @default.
• W3148153237 title "Different Phenomena in Magnetic/Electrical Properties of Co(II) and Ni(II) Isomorphous MOFs" @default.
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• W3148153237 doi "https://doi.org/10.1021/acsomega.1c00574" @default.
• W3148153237 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8028129" @default.
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• W3148153237 hasPublicationYear "2021" @default.
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