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- W3148200265 abstract "The thermal decomposition behavior of 3,4,5- triamino-1,2,4-triazole dinitramide was measured using a C-500 type Calvet microcalorimeter at four different tem- peratures under atmospheric pressure. The apparent activa- tion energy and pre-exponential factor of the exothermic decomposition reaction are 165.57 kJ mol -1 and 10 18.04 s -1 , respectively. The critical temperature of thermal explosion is 431.71 K. The entropy of activation (DS = ), enthalpy of activation (DH = ), and free energy of activation (DG = ) are 97.19 J mol -1 K -1 , 161.90 kJ mol -1 , and 118.98 kJ mol -1 , respectively. The self-accelerating decomposition temperature (TSADT) is 422.28 K. The spe- cific heat capacity of 3,4,5-triamino-1,2,4-triazole dinitra- mide was determined with a micro-DSC method and a theoretical calculation method. Specific heat capacity (J g -1 K -1 ) equation is Cp = 0.252 ? 3.131 9 10 -3 T (283.1 K T 353.2 K). The molar heat capacity of 3,4,5-triamino-1,2,4-triazole dinitramide is 264.52 J mol -1 K -1 at 298.15 K. The adiabatic time-to-explosion of 3,4,5-triamino-1,2,4-triazole dinitramide is calculated to be a certain value between 123.36 and 128.56 s." @default.
- W3148200265 created "2021-04-13" @default.
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- W3148200265 date "2010-01-01" @default.
- W3148200265 modified "2023-09-27" @default.
- W3148200265 title "Thermal behavior of 3,4,5-triamino-1,2,4-triazole dinitramide" @default.
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