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- W3148236520 abstract "Few-atom-thick two-dimensional (2D) molybdenum disulfide (MoS 2 ) monolayers possess numerous crucial applications in energy storage. Usually, the strategy of activating interfacial electron transfer was employed to promote their performance. Herein, we reshape the structure of materials to excite their subinterfacial and interfacial electron transfer for superior metal-ion batteries. As an example, we rationally design and reconfigure the structure of 2D MoS 2 and propose a new stable structure, B-MoS 2 , which has an S–Mo–S sandwich structure with a buckled square lattice. The B-MoS 2 monolayer is a promising anode material for magnesium-ion batteries (MgIBs) with a high capacity (921.3 mA h g −1 ) and a low averaged open circuit voltage (0.154 V). Multiscale underlying mechanisms for the storage of Mg and Li ions in MoS 2 are provided. Based on the electronic level, the high capacity is ascribed to the occurrence of interfacial and subinterfacial electron transfer between metal ions and B-MoS 2 . Based on the atomic level, the insertion-adsorption mechanism or adsorption-insertion mechanism is determined for different ion storage at B-MoS 2 . The intrinsic metallic property of B-MoS 2 and the enhanced electronic conductivity of Mg/B-MoS 2 systems as well as low migration barriers (∼0.604 eV) of Mg ions at MoS 2 suggest that the B-MoS 2 anode has fast charge/discharge rates. This work offers novel concepts (i.e. subinterfacial electron transfer and its activation) for superior energy storage materials, and proposes new multiscale underlying mechanisms for ion storage in the MoS 2 family." @default.
- W3148236520 created "2021-04-13" @default.
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- W3148236520 date "2021-09-01" @default.
- W3148236520 modified "2023-09-29" @default.
- W3148236520 title "Reshaping two-dimensional MoS2 for superior magnesium-ion battery anodes" @default.
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- W3148236520 doi "https://doi.org/10.1016/j.jcis.2021.04.002" @default.
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