FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3148294525> ?p ?o ?g. }

• W3148294525 endingPage "114" @default.
• W3148294525 startingPage "98" @default.
• W3148294525 abstract "To synthesize and investigate polyhydroxyalkanoates (PHAs) with different monomer composition and percentages and polymer films prepared from them. Various PHAs: homopolymer poly-3-hydroxybutyrate P(3HB) and 2-, 3-, and 4-component copolymers comprising various combinations of 3-hydroxybutyrate (3HB), 3-hydroxyvalerate (3HV), 4-hydroxybutyrate (4HB), and 3-hydroxyhexanoate (3HHx) monomers were synthesized under specialized conditions. Relationships were found between the monomer composition of PHAs and their molecular-weight and thermal properties and degree of crystallinity. All copolymers had decreased weight average molecular weights, Mw (to 390–600 kDa), and increased values of polydispersity (3.2–4.6) compared to the P(3HB). PHA copolymers showed different thermal behavior: an insignificant decrease in Tmelt and the presence of the second peak in the melting region and changes in parameters of crystallization and glass transition. At the same time, they retained thermostability, and the difference between Tmelt and Tdegr was at least 100–120 °C. Incorporation of 4HB, 3HV, and 3HHx monomer units into the 3-hydroxybutyrate chain caused changes in the amorphous to crystalline ratio and decreased the degree of crystallinity (Cx) to 20–40%. According to the degree to which the monomers reduced crystallinity, they were ranked as follows: 4HB – 3HHx – 3HV. A unique set of films was produced; their surface properties and physical/mechanical properties were studied as dependent on PHA composition; monomers other than 3-hydroxybutyrate were found to enhance hydrophilicity, surface development, and elasticity of polymer films. An innovative set of PHA copolymers was synthesized and solution-cast films were prepared from them; the copolymers and films were investigated as dependent on polymer chemical composition. Results obtained in the present study contribute to the solution of a critical issue of producing degradable polymer materials." @default.
• W3148294525 created "2021-04-13" @default.
• W3148294525 creator A5023955886 @default.
• W3148294525 creator A5025080780 @default.
• W3148294525 creator A5029705881 @default.
• W3148294525 creator A5035355536 @default.
• W3148294525 creator A5042464967 @default.
• W3148294525 creator A5045647904 @default.
• W3148294525 creator A5049775101 @default.
• W3148294525 creator A5077658071 @default.
• W3148294525 date "2021-07-01" @default.
• W3148294525 modified "2023-10-16" @default.
• W3148294525 title "Properties of degradable polyhydroxyalkanoates with different monomer compositions" @default.
• W3148294525 cites W1496521971 @default.
• W3148294525 cites W1822400406 @default.
• W3148294525 cites W1879791186 @default.
• W3148294525 cites W1965429036 @default.
• W3148294525 cites W1974548541 @default.
• W3148294525 cites W1975633127 @default.
• W3148294525 cites W1984620053 @default.
• W3148294525 cites W1988595986 @default.
• W3148294525 cites W1990039170 @default.
• W3148294525 cites W1995050000 @default.
• W3148294525 cites W1998003100 @default.
• W3148294525 cites W2004851192 @default.
• W3148294525 cites W2005544049 @default.
• W3148294525 cites W2011666062 @default.
• W3148294525 cites W2017192425 @default.
• W3148294525 cites W2022389041 @default.
• W3148294525 cites W2027972366 @default.
• W3148294525 cites W2037866493 @default.
• W3148294525 cites W2039517105 @default.
• W3148294525 cites W2042562325 @default.
• W3148294525 cites W2050783558 @default.
• W3148294525 cites W2053484261 @default.
• W3148294525 cites W2053788225 @default.
• W3148294525 cites W2056023823 @default.
• W3148294525 cites W2056778275 @default.
• W3148294525 cites W2059180958 @default.
• W3148294525 cites W2067139801 @default.
• W3148294525 cites W2069191542 @default.
• W3148294525 cites W2076904564 @default.
• W3148294525 cites W2079753398 @default.
• W3148294525 cites W2085411539 @default.
• W3148294525 cites W2098132892 @default.
• W3148294525 cites W2100306766 @default.
• W3148294525 cites W2104452062 @default.
• W3148294525 cites W2105860283 @default.
• W3148294525 cites W2122364241 @default.
• W3148294525 cites W2139302537 @default.
• W3148294525 cites W2142516657 @default.
• W3148294525 cites W2157976579 @default.
• W3148294525 cites W2163522404 @default.
• W3148294525 cites W2164191131 @default.
• W3148294525 cites W2166879168 @default.
• W3148294525 cites W219670351 @default.
• W3148294525 cites W2339228033 @default.
• W3148294525 cites W2348603664 @default.
• W3148294525 cites W2352013391 @default.
• W3148294525 cites W2530193201 @default.
• W3148294525 cites W2531171355 @default.
• W3148294525 cites W2559436898 @default.
• W3148294525 cites W2599366797 @default.
• W3148294525 cites W2608841876 @default.
• W3148294525 cites W2611648148 @default.
• W3148294525 cites W2740815623 @default.
• W3148294525 cites W2750580740 @default.
• W3148294525 cites W2755665789 @default.
• W3148294525 cites W2756270314 @default.
• W3148294525 cites W2781510895 @default.
• W3148294525 cites W2785056120 @default.
• W3148294525 cites W2792387971 @default.
• W3148294525 cites W2896016912 @default.
• W3148294525 cites W2903660848 @default.
• W3148294525 cites W2906561601 @default.
• W3148294525 cites W2908667510 @default.
• W3148294525 cites W2911812206 @default.
• W3148294525 cites W2938325311 @default.
• W3148294525 cites W2956617151 @default.
• W3148294525 cites W2970291595 @default.
• W3148294525 cites W2971087544 @default.
• W3148294525 cites W2977946388 @default.
• W3148294525 cites W2987280276 @default.
• W3148294525 cites W298995639 @default.
• W3148294525 cites W2997425038 @default.
• W3148294525 cites W2997575781 @default.
• W3148294525 cites W3005668855 @default.
• W3148294525 cites W3011721046 @default.
• W3148294525 cites W3015241130 @default.
• W3148294525 cites W3027645984 @default.
• W3148294525 cites W3049268981 @default.
• W3148294525 cites W3054950769 @default.
• W3148294525 cites W3091977128 @default.
• W3148294525 cites W3093292829 @default.
• W3148294525 cites W3094253913 @default.
• W3148294525 cites W3094871402 @default.
• W3148294525 cites W3111006364 @default.
• W3148294525 cites W3125499593 @default.

• next