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- W3148300476 abstract "Boronic acid-catalyzed regioselective Koenigs-Knorr-type glycosylation is presented. The reaction of an unprotected or partially protected glycosyl acceptor with a glycosyl halide donor in the presence of silver oxide and a low catalytic amount of imidazole-containing boronic acid was found to proceed smoothly, which enables construction of a 1,2-trans glycosidic linkage with high regioselectivities. This is the first example of the use of a boronic acid catalyst to initiate regioselective glycosylation via the activation of cis-vicinal diols in glycosyl acceptors." @default.
- W3148300476 created "2021-04-13" @default.
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- W3148300476 date "2021-04-08" @default.
- W3148300476 modified "2023-09-23" @default.
- W3148300476 title "Boronic Acid-Catalyzed Regioselective Koenigs–Knorr-Type Glycosylation" @default.
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- W3148300476 doi "https://doi.org/10.1021/acs.joc.1c00130" @default.
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