Matches in SemOpenAlex for { <https://semopenalex.org/work/W3148346319> ?p ?o ?g. }
- W3148346319 endingPage "5778" @default.
- W3148346319 startingPage "5771" @default.
- W3148346319 abstract "The discovery of pyramidal inversion has continued to impact modern organic and organometallic chemistry. Sequential alkylation reactions of an N-heterocyclic carbene (NHC) ligated dicarbondiphosphide 1 with RI (R = Me, Et, or iBu) and ZnMe2 give rise to the highly stereoselective synthesis of cis-1,3-diphosphetanes 3. cis-3 is conformationally favorable at room temperature, whereas inversion to trans-3 is observed at 110 °C. One-electron oxidation of cis-3 with Fc+(BArF) (Fc = [Fe(C5H5)2]; BArF = [B(3,5-(CF3)2C6H3)4)]−) leads to the stereoselective formation of trans-1,3-diphosphetane radical cation salts 3•+(BArF), which can be reversibly transformed to cis-3 upon one-electron reduction. Salts 3•+(BArF) represent the first examples of 1,3-diphosphetane radical cations. These results provide a potential application of planar four-membered heterocycle-based building blocks for electrically fueled molecular switches." @default.
- W3148346319 created "2021-04-13" @default.
- W3148346319 creator A5000775028 @default.
- W3148346319 creator A5002170896 @default.
- W3148346319 creator A5004075655 @default.
- W3148346319 creator A5005281741 @default.
- W3148346319 creator A5037201526 @default.
- W3148346319 creator A5067690677 @default.
- W3148346319 creator A5073568638 @default.
- W3148346319 creator A5078835568 @default.
- W3148346319 creator A5084416597 @default.
- W3148346319 date "2021-03-29" @default.
- W3148346319 modified "2023-10-14" @default.
- W3148346319 title "Reversible Stereoisomerization of 1,3-Diphosphetane Frameworks Revealed by a Single-Electron Redox Approach" @default.
- W3148346319 cites W1458390031 @default.
- W3148346319 cites W1983102412 @default.
- W3148346319 cites W1984608626 @default.
- W3148346319 cites W1986234676 @default.
- W3148346319 cites W1987010198 @default.
- W3148346319 cites W1988165957 @default.
- W3148346319 cites W1992629622 @default.
- W3148346319 cites W1992938286 @default.
- W3148346319 cites W1993633160 @default.
- W3148346319 cites W1999001149 @default.
- W3148346319 cites W2007189036 @default.
- W3148346319 cites W2007869175 @default.
- W3148346319 cites W2019155364 @default.
- W3148346319 cites W2026473737 @default.
- W3148346319 cites W2030489166 @default.
- W3148346319 cites W2033179635 @default.
- W3148346319 cites W2041049025 @default.
- W3148346319 cites W2052114811 @default.
- W3148346319 cites W2054940585 @default.
- W3148346319 cites W2058161057 @default.
- W3148346319 cites W2059433943 @default.
- W3148346319 cites W2060013781 @default.
- W3148346319 cites W2063805396 @default.
- W3148346319 cites W2064903989 @default.
- W3148346319 cites W2068871883 @default.
- W3148346319 cites W2069269262 @default.
- W3148346319 cites W2073245585 @default.
- W3148346319 cites W2079392340 @default.
- W3148346319 cites W2080007090 @default.
- W3148346319 cites W2080323928 @default.
- W3148346319 cites W2093953452 @default.
- W3148346319 cites W2094839432 @default.
- W3148346319 cites W2112455205 @default.
- W3148346319 cites W2135112612 @default.
- W3148346319 cites W2147440332 @default.
- W3148346319 cites W2153946131 @default.
- W3148346319 cites W2168542043 @default.
- W3148346319 cites W2236745200 @default.
- W3148346319 cites W2315739595 @default.
- W3148346319 cites W2321114398 @default.
- W3148346319 cites W2324787465 @default.
- W3148346319 cites W2328097957 @default.
- W3148346319 cites W2331919097 @default.
- W3148346319 cites W2337426430 @default.
- W3148346319 cites W2409613114 @default.
- W3148346319 cites W2493630713 @default.
- W3148346319 cites W2536947349 @default.
- W3148346319 cites W2604156473 @default.
- W3148346319 cites W2608989684 @default.
- W3148346319 cites W2744834133 @default.
- W3148346319 cites W2749358101 @default.
- W3148346319 cites W2767245009 @default.
- W3148346319 cites W2800175249 @default.
- W3148346319 cites W2808385755 @default.
- W3148346319 cites W2811352597 @default.
- W3148346319 cites W2893965452 @default.
- W3148346319 cites W2902016400 @default.
- W3148346319 cites W2909413067 @default.
- W3148346319 cites W2912675719 @default.
- W3148346319 cites W2914353745 @default.
- W3148346319 cites W2921485378 @default.
- W3148346319 cites W2940350421 @default.
- W3148346319 cites W2946703191 @default.
- W3148346319 cites W3019233392 @default.
- W3148346319 cites W3023675346 @default.
- W3148346319 cites W3084111016 @default.
- W3148346319 cites W4210966973 @default.
- W3148346319 doi "https://doi.org/10.1021/acs.inorgchem.1c00064" @default.
- W3148346319 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33780618" @default.
- W3148346319 hasPublicationYear "2021" @default.
- W3148346319 type Work @default.
- W3148346319 sameAs 3148346319 @default.
- W3148346319 citedByCount "4" @default.
- W3148346319 countsByYear W31483463192022 @default.
- W3148346319 countsByYear W31483463192023 @default.
- W3148346319 crossrefType "journal-article" @default.
- W3148346319 hasAuthorship W3148346319A5000775028 @default.
- W3148346319 hasAuthorship W3148346319A5002170896 @default.
- W3148346319 hasAuthorship W3148346319A5004075655 @default.
- W3148346319 hasAuthorship W3148346319A5005281741 @default.
- W3148346319 hasAuthorship W3148346319A5037201526 @default.
- W3148346319 hasAuthorship W3148346319A5067690677 @default.
- W3148346319 hasAuthorship W3148346319A5073568638 @default.
- W3148346319 hasAuthorship W3148346319A5078835568 @default.