Matches in SemOpenAlex for { <https://semopenalex.org/work/W3148392811> ?p ?o ?g. }
- W3148392811 endingPage "2033" @default.
- W3148392811 startingPage "2017" @default.
- W3148392811 abstract "Abstract The reaction chemistry of Fe 2 (CO) 9 ( 10 ) with ferrocenenyl dichlorophosphines of different substitution is discussed. Single FcPCl 2 , ( 5 ) as well as 1,1’‐ ( 6 ) and 1,2‐ ( 9 ) difunctionalized phosphines were used, of which 6 and 9 , were prepared in a novel straightforward synthetic process. Substrate 5 gave butterfly‐shaped Fe 2 (CO) 6 (μ 2 ‐Cl)(μ 2 ‐PFcCl) and Fe 2 (CO) 6 (μ 2 ‐PFcR 1 )(μ 2 ‐PFcR 2 ) (R 1 , R 2 =Cl, H). In addition, nido ‐Fe 3 (CO) 10 (μ 3 ‐PFc) and nido ‐Fe 3 (CO) 9 (μ 3 ‐PFc) 2 were obtained. 1,1’‐Functionalized 6 bridges both ends of the Fe 2 (CO) 6 entity. Therein, the so far smallest non‐binding P⋅⋅⋅P distance (2.7674(12) Å) between both 1,1’‐substituents is observed. Additionally, an ‘organometallic octabisvalene ’, containing two [2]ferrocenophane entities was obtained. The eight‐membered cyclic structure is twisted by 35.31(9)° regarding their ferrocenyl axis. Usage of 1,2‐(PCl 2 ) 2 functionalized 9 produced two isomers of a P−P connected dimer, which coordinates towards two independent Fe 2 (CO) 6 fragments in a novel μ,μ’,κ 8 or bis(μ,κ 4 ) fashion, resulting in a meso isomer with a planar core, and a racem mixture, possessing a pocket‐type structure. The latter shows the so far shortest observed P⋅⋅⋅P distance of 2.950(7) Å between two ortho P atoms of a ferrocenyl backbone. The results confirm that the geometric properties of ferrocenyls featuring 1,1’‐ and 1,2‐substitution patterns are not comparable with phenyl‐based analogues. X‐ray single crystal solid state structures, and DFT calculations were carried out." @default.
- W3148392811 created "2021-04-13" @default.
- W3148392811 creator A5015080148 @default.
- W3148392811 creator A5027059038 @default.
- W3148392811 creator A5039877065 @default.
- W3148392811 creator A5066807975 @default.
- W3148392811 creator A5088536141 @default.
- W3148392811 creator A5088665202 @default.
- W3148392811 date "2021-05-13" @default.
- W3148392811 modified "2023-10-18" @default.
- W3148392811 title "Structural Variety of Iron Carbonyl Clusters Featuring Ferrocenylphosphines" @default.
- W3148392811 cites W1488393531 @default.
- W3148392811 cites W1536671469 @default.
- W3148392811 cites W1558007860 @default.
- W3148392811 cites W1722557319 @default.
- W3148392811 cites W1779459399 @default.
- W3148392811 cites W1806331493 @default.
- W3148392811 cites W1951893327 @default.
- W3148392811 cites W1967844093 @default.
- W3148392811 cites W1968520552 @default.
- W3148392811 cites W1968564692 @default.
- W3148392811 cites W1970813331 @default.
- W3148392811 cites W1970973469 @default.
- W3148392811 cites W1977450392 @default.
- W3148392811 cites W1979788818 @default.
- W3148392811 cites W1980365422 @default.
- W3148392811 cites W1982912096 @default.
- W3148392811 cites W1990170643 @default.
- W3148392811 cites W1996550247 @default.
- W3148392811 cites W1999968977 @default.
- W3148392811 cites W2003107800 @default.
- W3148392811 cites W2010209096 @default.
- W3148392811 cites W2015645223 @default.
- W3148392811 cites W2016166906 @default.
- W3148392811 cites W2020539372 @default.
- W3148392811 cites W2022673999 @default.
- W3148392811 cites W2024065543 @default.
- W3148392811 cites W2025076359 @default.
- W3148392811 cites W2028905647 @default.
- W3148392811 cites W2029194528 @default.
- W3148392811 cites W2030531643 @default.
- W3148392811 cites W2032299329 @default.
- W3148392811 cites W2033193282 @default.
- W3148392811 cites W2033518497 @default.
- W3148392811 cites W2034700558 @default.
- W3148392811 cites W2037208939 @default.
- W3148392811 cites W2039218400 @default.
- W3148392811 cites W2040338073 @default.
- W3148392811 cites W2040494928 @default.
- W3148392811 cites W2041126038 @default.
- W3148392811 cites W2041608759 @default.
- W3148392811 cites W2044443975 @default.
- W3148392811 cites W2044477622 @default.
- W3148392811 cites W2045236580 @default.
- W3148392811 cites W2047247077 @default.
- W3148392811 cites W2049807213 @default.
- W3148392811 cites W2050334066 @default.
- W3148392811 cites W2050397003 @default.
- W3148392811 cites W2055200758 @default.
- W3148392811 cites W2060757838 @default.
- W3148392811 cites W2065402153 @default.
- W3148392811 cites W2066863431 @default.
- W3148392811 cites W2066932188 @default.
- W3148392811 cites W2067718414 @default.
- W3148392811 cites W2074303618 @default.
- W3148392811 cites W2075803743 @default.
- W3148392811 cites W2076541829 @default.
- W3148392811 cites W2081732872 @default.
- W3148392811 cites W2081885195 @default.
- W3148392811 cites W2082057770 @default.
- W3148392811 cites W2086057949 @default.
- W3148392811 cites W2092624897 @default.
- W3148392811 cites W2093020858 @default.
- W3148392811 cites W2123334472 @default.
- W3148392811 cites W2128179591 @default.
- W3148392811 cites W2131350133 @default.
- W3148392811 cites W2137072024 @default.
- W3148392811 cites W2137376755 @default.
- W3148392811 cites W2148066840 @default.
- W3148392811 cites W2155148122 @default.
- W3148392811 cites W2161358663 @default.
- W3148392811 cites W2230178110 @default.
- W3148392811 cites W2312186160 @default.
- W3148392811 cites W2328225160 @default.
- W3148392811 cites W2334885198 @default.
- W3148392811 cites W2400152421 @default.
- W3148392811 cites W2508033081 @default.
- W3148392811 cites W2510718413 @default.
- W3148392811 cites W2516745878 @default.
- W3148392811 cites W2518039310 @default.
- W3148392811 cites W2528182145 @default.
- W3148392811 cites W2557525611 @default.
- W3148392811 cites W2563221005 @default.
- W3148392811 cites W2591009929 @default.
- W3148392811 cites W2622933425 @default.
- W3148392811 cites W2738757219 @default.
- W3148392811 cites W2739439285 @default.
- W3148392811 cites W2740269599 @default.