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• W3148731285 abstract "In this study, co-gasification behaviors and synergistic interaction of bituminous coal and walnut shell under CO 2 atmosphere were investigated by using a thermogravimetric analyzer. The evolution of physicochemical properties of samples was characterized with an inductively coupled plasma emission spectrometer, an X-ray fluorescence spectrometer, and an X-ray diffractometer. The results indicated that the addition of walnut shell significantly enhanced the gasification reactivity of coal, and coal/biomass blend ratio of 7:3 showed an intense gasification. Moreover, a significant co-gasification interaction was observed in the char gasification stage and demonstrated that a high coal/biomass blend ratio induced the formation of amorphous carbons and further accelerated the co-gasification reaction. Meanwhile, the active inorganics were severely released as 30 wt % bituminous coal added to walnut shell, causing a deteriorative gasification reactivity. Furthermore, three kinetic models illustrated that the coal/biomass blend ratio of 7:3 required a minimum activation energy to initialize gasification. The findings in this work would be beneficial for revealing the co-gasification mechanism of biomass and coal, and provide a useful basis on their multi-scale applications. • Low coal/biomass blend ratio significantly reduced co-gasification reactivity. • Accelerated liberation of reactive inorganics resulted in severe co-gasification inhibition. • 70 wt % additions of bituminous coal induced formation of amorphous carbonaceous compounds. • The average activation energy was minimum by blending 70 wt % bituminous coal." @default.
• W3148731285 created "2021-04-13" @default.
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• W3148731285 date "2021-08-01" @default.
• W3148731285 modified "2023-10-14" @default.
• W3148731285 title "Interaction and kinetic analysis of co-gasification of bituminous coal with walnut shell under CO2 atmosphere: Effect of inorganics and carbon structures" @default.
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• W3148731285 doi "https://doi.org/10.1016/j.renene.2021.03.097" @default.
• W3148731285 hasPublicationYear "2021" @default.
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