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• W3148731594 endingPage "5979" @default.
• W3148731594 startingPage "5969" @default.
• W3148731594 abstract "Spin states of iron often direct the selectivity in oxidation catalysis by iron complexes using hydrogen peroxide (H2O2) on an oxidant. While low-spin iron(III) hydroperoxides display stereoselective C-H bond hydroxylation, the reactions are nonstereoselective with high-spin iron(II) catalysts. The catalytic studies with a series of high-spin iron(II) complexes of N4 ligands with H2O2 and Sc3+ reported here reveal that the Lewis acid promotes catalytic C-H bond hydroxylation with high chemo- and stereoselectivity. This reactivity pattern is observed with iron(II) complexes containing two cis-labile sites. The enhanced selectivity for C-H bond hydroxylation catalyzed by the high-spin iron(II) complexes in the presence of Sc3+ parallels that of the low-spin iron catalysts. Furthermore, the introduction of multimetal centers enhances the activity and selectivity of the iron catalyst. The study provides insights into the development of peroxide-dependent bioinspired catalysts for the selective oxygenation of C-H bonds without the restriction of using iron complexes of strong-field ligands." @default.
• W3148731594 created "2021-04-13" @default.
• W3148731594 creator A5037909745 @default.
• W3148731594 creator A5063525254 @default.
• W3148731594 creator A5079628284 @default.
• W3148731594 date "2021-03-30" @default.
• W3148731594 modified "2023-09-27" @default.
• W3148731594 title "Enhancing Chemo- and Stereoselectivity in C–H Bond Oxygenation with H₂O₂ by Nonheme High-Spin Iron Catalysts: The Role of Lewis Acid and Multimetal Centers" @default.
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• W3148731594 doi "https://doi.org/10.1021/acs.inorgchem.1c00397" @default.
• W3148731594 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33784082" @default.
• W3148731594 hasPublicationYear "2021" @default.
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