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• W3148738690 abstract "abstract The evidence that oxidized phospholipids play a role in signaling, apoptotic events and in age-relateddiseases is responsible for the increasing interest for the study of this subject. Phospholipid changesinduced by oxidative reactions yield a huge number of structurally different oxidation products whichdifficult their isolation and characterization. Mass spectrometry (MS), and tandem mass spectrometry(MS/MS)usingthesoftionizationmethods(electrosprayandmatrix-assistedlaserdesorptionionization)isoneofthefinestapproachesforthestudyofoxidizedphospholipids.Productionsintandemmassspectraof oxidized phospholipids, allow identifying changes in the fatty acyl chain and specific features such aspresenceofnewfunctionalgroupsinthemoleculeandtheirlocationalongthefattyacylchain.Thisreviewdescribestheworkpublishedontheuseofmassspectrometryinidentifyingoxidizedphospholipidsfromthe different classes.© 2008 Elsevier Ireland Ltd. All rights reserved. Contents 1. Introduction 21.1. Biological activity of oxidized glycerophospholipids 21.2. The nature of oxidized glycerophospholipids 21.3. Mass spectrometry analysis of oxidized phospholipids 22. Characterization of oxidized phospholipids 32.1. Glycerophosphocholines 32.1.1. Characteristic fragmentation of PC under MS/MS 42.1.2. Identification of short chain oxidation products of PC 42.1.3. Identification of long-chain oxidation products of PC 52.1.4. Identification of PC adducts 72.2. Glycerophosphoethanolamine 72.3. Glycerophosphoserine 82.4. Cardiolipin 92.5. Other phospholipids 93. Future perspectives 10References 10" @default.
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• W3148738690 date "2008-01-01" @default.
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• W3148738690 title "Chemistry and Physics of Lipids" @default.
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