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- W314901211 abstract "Using a previously developed labelled atom method, the rate constant was determined for the reaction of hydrogen atoms with n-hexane at pyrolysis temperatures. The thermal decomposition of n-hexane was carried out in a xenon stream at 700-800/sup 0/C with total reaction pressure 13.3 kPa and partial n-hexane pressure 1.3 kPa (mixture I) and 6.7 kPa (mixture II). The runs were performed in a laboratory vacuum flow system with ground quartz fluidized bed. Propylene-/sup 14/C was used as the labelled marker with the label at the double bond (H/sub 2/C = /sup 14/C-CH/sub 3/) and 2.8 x 10/sup 4/ counts/cm/sup 3/ . min specific radioactivity. The concentration of radioactive propylene in the initial mixture was 1-2 vol. % (relative to hexane)." @default.
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- W314901211 date "1982-03-01" @default.
- W314901211 modified "2023-09-24" @default.
- W314901211 title "Determination of the rate constants for the substitution of hydrogen atoms by higher normal paraffin hydrocarbons" @default.
- W314901211 hasPublicationYear "1982" @default.
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