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- W3149053715 abstract "Achiral diacetylene 10,12-pentacosadinoic acid (PCDA) and a chiral low-molecular-weight organogelator could form co-gel in organic solvent and it could be polymerized in the presence of Zn(II) ion or in the corresponding xerogel under UV-irradiation. Optically active polydiacetylene (PDA) were subsequently obtained. Supramolecular chirality of PDA could be controlled by the chirality of gelators. Left-handed and right-handed helical fibers were obtained by using Land D-gelators in xerogels respectively, and CD spectra exhibited mirror-image circular dichroism. The PDA in xerogel exhibited typical blue-to-red transition responsive to the temperature and pH, while the supramolecular chirality of PDA showed a corresponding change." @default.
- W3149053715 created "2021-04-13" @default.
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- W3149053715 date "2010-01-01" @default.
- W3149053715 modified "2023-09-23" @default.
- W3149053715 title "Preparation of optical active polydiacetylene through gelating and the control of supramolecular chirality" @default.
- W3149053715 hasPublicationYear "2010" @default.
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