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- W3149187470 abstract "The kinetics of electrochemical reaction of Nd~(3+) reduced on liquid Gaelectrode has been studied by cyclic voltammetry (CV) in molten chloride at 1073K.The results show that the reduction of Nd~(3+)? on Ga electrode proceeds in consequenttwo steps. For the first step, it is found to be a diffusion controlled reversible re-action at higher rate of potential scan, i. c., Nd~(3+)+e=Nd~(2+) and an irreversible rea-ction controlled by following chemical reaction at lower rate, i. c., Nd~(3+)+e?Nd~(2+)+mCl NdCl'_m~(-m). For the second step, alloying reaction of deposited Nd with Ga canbe observed and the reaction is found to irreversible, Nd~(2+)+2e→Nd(Ga). The stand-ard rate constant of this reactiin is estimated to be 7.0×10~(-3) cm/s." @default.
- W3149187470 created "2021-04-13" @default.
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- W3149187470 date "1991-01-01" @default.
- W3149187470 modified "2023-09-23" @default.
- W3149187470 title "ELECTROCHEMICAL BEHAVIOUR OF Nd~3+ REDUCED ON LIQUID Ga ELECTRODE IN MOLTEN CHLORIDE" @default.
- W3149187470 hasPublicationYear "1991" @default.
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