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- W3149624923 abstract "Ca α-Sialon compacts pressurelessly-sintered tothe intermediate temperature (1 450℃) were investigated with TEM for an overall composition Ca1.8Si6.6Al5.4O1.8N14.2. It was found that in most cases, the newly-formed α-Sialon grains had no epitaxial orientation relationship with the Si3N4 particles; only occasionally heteroepitaxial nucleation of α-Sialon on α-Si3N4 was detected. Further EDAX analysis revealed a much higher Ca concentration in the non-epi-taxially nucleated α-Sialon than in the heteroepitaxially nucleated a-Sialon. Thus a possible correlation between the concentration of metal cations in the α-Sialon structure and the nucleation mechanism has been proposed, i.e. α-Sialon compositions with higher Ca concentration show a stronger trend of non-epitaxial nucleation." @default.
- W3149624923 created "2021-04-13" @default.
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- W3149624923 date "2001-01-01" @default.
- W3149624923 modified "2023-09-25" @default.
- W3149624923 title "TEM observation on nucleation of Ca α-Sialon" @default.
- W3149624923 hasPublicationYear "2001" @default.
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