FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3149627462> ?p ?o ?g. }

• W3149627462 endingPage "2342" @default.
• W3149627462 startingPage "2331" @default.
• W3149627462 abstract "Abstract In‐situ NMR spectroscopic analysis of homogeneous reactions is an essential tool for mechanistic analysis in organic and organometallic chemistry. However, rapid non‐equilibrium reactions, that are initiated by mixing, require specialized approaches. We report herein on a study of the factors that ensure quantitative results in a recently‐developed technique for stopped‐flow NMR spectroscopy. The influence of some of the key parameters on quantitation is studied by 19 F NMR spectroscopic analysis of the kinetics and activation parameters for the base‐catalyzed protodeboronation of highly‐reactive polyfluorinated arylboronic acids, with half‐lives as low as 0.1 seconds. The effects of spin relaxation, pre‐magnetization, heat‐transfer versus reaction enthalpy, and mixing‐efficiency are analyzed in detail. We also compare and contrast choice of pulse angle, interscan delay, and use of pseudo real‐time by interleaving, as means to achieve an optimal balance between temporal resolution and sensitivity." @default.
• W3149627462 created "2021-04-13" @default.
• W3149627462 creator A5004567326 @default.
• W3149627462 creator A5007342740 @default.
• W3149627462 creator A5024916835 @default.
• W3149627462 creator A5026806026 @default.
• W3149627462 creator A5064631717 @default.
• W3149627462 creator A5064688915 @default.
• W3149627462 date "2021-05-05" @default.
• W3149627462 modified "2023-10-18" @default.
• W3149627462 title "Stopped‐Flow ¹⁹ F NMR Spectroscopic Analysis of a Protodeboronation Proceeding at the Sub‐Second Time‐Scale" @default.
• W3149627462 cites W1580392549 @default.
• W3149627462 cites W1970121803 @default.
• W3149627462 cites W1979358832 @default.
• W3149627462 cites W1981159786 @default.
• W3149627462 cites W1981596913 @default.
• W3149627462 cites W1985767604 @default.
• W3149627462 cites W1991735545 @default.
• W3149627462 cites W1993602486 @default.
• W3149627462 cites W1997727558 @default.
• W3149627462 cites W1999737425 @default.
• W3149627462 cites W2001575435 @default.
• W3149627462 cites W2002530779 @default.
• W3149627462 cites W2017329774 @default.
• W3149627462 cites W2031510492 @default.
• W3149627462 cites W2033552143 @default.
• W3149627462 cites W2041072491 @default.
• W3149627462 cites W2041627289 @default.
• W3149627462 cites W2044865665 @default.
• W3149627462 cites W2045762632 @default.
• W3149627462 cites W2046928217 @default.
• W3149627462 cites W2052335205 @default.
• W3149627462 cites W2055557864 @default.
• W3149627462 cites W2057442814 @default.
• W3149627462 cites W2057844675 @default.
• W3149627462 cites W2064976486 @default.
• W3149627462 cites W2070302549 @default.
• W3149627462 cites W2074770586 @default.
• W3149627462 cites W2076283593 @default.
• W3149627462 cites W2081276710 @default.
• W3149627462 cites W2083741754 @default.
• W3149627462 cites W2090756053 @default.
• W3149627462 cites W2124292770 @default.
• W3149627462 cites W2155501296 @default.
• W3149627462 cites W2192893032 @default.
• W3149627462 cites W2327580020 @default.
• W3149627462 cites W2329971874 @default.
• W3149627462 cites W2333847793 @default.
• W3149627462 cites W2406492823 @default.
• W3149627462 cites W2462322978 @default.
• W3149627462 cites W2489471333 @default.
• W3149627462 cites W2528633920 @default.
• W3149627462 cites W2563642243 @default.
• W3149627462 cites W2617626515 @default.
• W3149627462 cites W2742364082 @default.
• W3149627462 cites W2746362507 @default.
• W3149627462 cites W2794744690 @default.
• W3149627462 cites W2886873330 @default.
• W3149627462 cites W2964713109 @default.
• W3149627462 cites W3044591481 @default.
• W3149627462 cites W3071306231 @default.
• W3149627462 cites W3109632316 @default.
• W3149627462 cites W3118458191 @default.
• W3149627462 cites W3132472277 @default.
• W3149627462 cites W4249490683 @default.
• W3149627462 doi "https://doi.org/10.1002/ejoc.202100290" @default.
• W3149627462 hasPublicationYear "2021" @default.
• W3149627462 type Work @default.
• W3149627462 sameAs 3149627462 @default.
• W3149627462 citedByCount "14" @default.
• W3149627462 countsByYear W31496274622021 @default.
• W3149627462 countsByYear W31496274622022 @default.
• W3149627462 countsByYear W31496274622023 @default.
• W3149627462 crossrefType "journal-article" @default.
• W3149627462 hasAuthorship W3149627462A5004567326 @default.
• W3149627462 hasAuthorship W3149627462A5007342740 @default.
• W3149627462 hasAuthorship W3149627462A5024916835 @default.
• W3149627462 hasAuthorship W3149627462A5026806026 @default.
• W3149627462 hasAuthorship W3149627462A5064631717 @default.
• W3149627462 hasAuthorship W3149627462A5064688915 @default.
• W3149627462 hasBestOaLocation W31496274621 @default.
• W3149627462 hasConcept C103319777 @default.
• W3149627462 hasConcept C113196181 @default.
• W3149627462 hasConcept C121332964 @default.
• W3149627462 hasConcept C126838900 @default.
• W3149627462 hasConcept C132482357 @default.
• W3149627462 hasConcept C138777275 @default.
• W3149627462 hasConcept C143409427 @default.
• W3149627462 hasConcept C147789679 @default.
• W3149627462 hasConcept C148898269 @default.
• W3149627462 hasConcept C15744967 @default.
• W3149627462 hasConcept C161790260 @default.
• W3149627462 hasConcept C178790620 @default.
• W3149627462 hasConcept C185592680 @default.
• W3149627462 hasConcept C2776029896 @default.
• W3149627462 hasConcept C27826641 @default.
• W3149627462 hasConcept C62520636 @default.
• W3149627462 hasConcept C66882249 @default.

• next