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- W3149743229 abstract "• Base mediated [4 + 2] type cyclocondensation of ketoester with ynone. • 3,5- and poly-substituted phenols were prepared. • No metal catalyst, oxidant and no auxiliary group were utilized. • The reaction of benzoyl acetone with ynone provides 3,4,5-trisubstituted phenol. A new [4 + 2] type cyclocondensation was developed to prepare 3,5- and poly-substituted phenols using aryl ketoesters and ynones as the starting materials; Various substrates, such as aryl-, heteroaryl ketoesters and aryl-, vinyl-, alkyl substituted ynones, were employed. In addition, extending the substrate scope to benzoyl acetone provided 3,4,5-trisubstituted phenols." @default.
- W3149743229 created "2021-04-13" @default.
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- W3149743229 date "2021-05-01" @default.
- W3149743229 modified "2023-09-27" @default.
- W3149743229 title "Synthesis of di- and poly-substituted phenols via [4 + 2] type cyclo-condensation" @default.
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- W3149743229 doi "https://doi.org/10.1016/j.tetlet.2021.153031" @default.
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