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- W3149786905 abstract "The viscosity (h) of {1,4-butanediol (i) + α-, or β-, or γ-picoline (j)}binary mixtures have been measured and reported at 303.15, 308.15, 313.15 and 318.15 K over the entire range of composition. Viscosity deviation ( ∆ h ) and excess Gibbs energy of activation of viscous flow ( ∆G* E ) based on Eyring’s theory have been evaluated and the results fitted to the Redlich-Kister equation. The ∆h values are observed to be negative over the entire range of composition for (1,4-butanediol+α-picoline), (1,4-butanediol+β-picoline) and (1,4-butanediol+γ-picoline) systems. The experimental viscosity data have been compared with some well-known equations of Frenkel, modified Frenkel approach and predictive ones like McAllister, Grunberg-Nissan, Hind et al ., Tamura Kurata and Katti-Chaudhri. The effects of molecular sizes and shapes of the component molecules on the molecular interactions present thereof in the mixtures have been discussed." @default.
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- W3149786905 date "2020-10-12" @default.
- W3149786905 modified "2023-09-27" @default.
- W3149786905 title "Molecular interaction in binary mixtures of 1,4-butanediol+picolines: Viscometric approach" @default.
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