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- W3149854973 abstract "A palladium-catalyzed intermolecular cascade (4+3) cyclocondensation of salicylaldehydes and vinylcyclopropanes is reported. A key feature of the reaction is the use of a phosphonate group as an acceptor moiety on the cyclopropane, exploiting its propensity to undergo olefination with aldehydes. Subsequent O-allylation enabled the formation of a range of substituted benzoxepinsWith a novel chiral ligand, the products were obtained in generally good yield and with reasonable enantioselectivity." @default.
- W3149854973 created "2021-04-13" @default.
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- W3149854973 date "2021-05-26" @default.
- W3149854973 modified "2023-10-14" @default.
- W3149854973 title "Palladium‐Catalyzed Cascade to Benzoxepins by Using Vinyl‐Substituted Donor–Acceptor Cyclopropanes" @default.
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- W3149854973 doi "https://doi.org/10.1002/anie.202102862" @default.
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