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- W3149969093 abstract "A series o f five trifluoroacetophenones and five phenyl trifluoromethyl carbinols have been synthesized and their ionizatio~i constants iri water measured. T h e y are t h e unsubst i tuted, p-methoxy, p-methyl, ni-bromo, and ?la-nitro compounds. T h e ketones exist as hydrates in aqueous solution and each is about two PIC units stronger than t h e corresponding alcohol. T h e acidities o f both series are correlated b y t h e H a m m e t t relation with p values o f 1.11 and 1.01 for the ketone hydrates a ~ i d alcohols respectively. T h e acid strengths vary from a PIC, o f 9.18 for ni-nitro-ol,ol,ol-trifluoroacetopheno~ t 12.24 for p-methoxyphenyl trifluoromethyl carbinol." @default.
- W3149969093 created "2021-04-13" @default.
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- W3149969093 date "2006-01-01" @default.
- W3149969093 modified "2023-09-27" @default.
- W3149969093 title "THE ACIDITY OF SOME AROMATIC FLUORO ALCOHOLS AND KETONES" @default.
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