Matches in SemOpenAlex for { <https://semopenalex.org/work/W3150277572> ?p ?o ?g. }
- W3150277572 endingPage "2100114" @default.
- W3150277572 startingPage "2100114" @default.
- W3150277572 abstract "Thermoresponsive polymers are frequently involved in the development of materials for various applications. Here, polymers containing poly(2- benzhydryl-2-oxazine) (pBhOzi) repeating units are described for the first time. The homopolymer pBhOzi and an ABA type amphiphile comprising two flanking hydrophilic A blocks of poly(2-methyl-2-oxazoline) (pMeOx) and the hydrophobic aromatic pBhOzi central B block (pMeOx-b-pBhOzi-b-pMeOx) are synthesized and the latter is shown to exhibit inverse thermogelling properties at concentrations of 20 wt.% in water. This behavior stands in contrast to a homologue ABA amphiphile consisting of a central poly(2-benzhydryl-2-oxazoline) block (pMeOx-b-pBhOx-b-pMeOx). No inverse thermogelling is observed with this polymer even at 25 wt.%. For 25 wt.% pMeOx-b-pBhOzi-b-pMeOx, a surprisingly high storage modulus of ≈22 kPa and high values for the yield and flow points of 480 Pa and 1.3 kPa are obtained. Exceeding the yield point, pronounced shear thinning is observed. Interestingly, only little difference between self-assemblies of pMeOx-b-pBhOzi-b-pMeOx and pMeOx-b-pBhOx-b-pMeOx is observed by dynamic light scattering while transmission electron microscopy images suggest that the micelles of pMeOx-b-pBhOzi-b-pMeOx interact through their hydrophilic coronas, which is probably decisive for the gel formation. Overall, this study introduces new building blocks for poly(2-oxazoline) and poly(2-oxazine)-based self-assemblies, but additional studies will be needed to unravel the exact mechanism." @default.
- W3150277572 created "2021-04-13" @default.
- W3150277572 creator A5002985330 @default.
- W3150277572 creator A5010196373 @default.
- W3150277572 creator A5021184671 @default.
- W3150277572 creator A5025070309 @default.
- W3150277572 creator A5053474293 @default.
- W3150277572 creator A5056461337 @default.
- W3150277572 creator A5086039148 @default.
- W3150277572 date "2021-08-02" @default.
- W3150277572 modified "2023-10-17" @default.
- W3150277572 title "ABA Type Amphiphiles with Poly(2‐benzhydryl‐2‐oxazine) Moieties: Synthesis, Characterization and Inverse Thermogelation" @default.
- W3150277572 cites W1563515257 @default.
- W3150277572 cites W191263453 @default.
- W3150277572 cites W1957062804 @default.
- W3150277572 cites W1969360633 @default.
- W3150277572 cites W2019826249 @default.
- W3150277572 cites W2020515905 @default.
- W3150277572 cites W2027478886 @default.
- W3150277572 cites W2030419906 @default.
- W3150277572 cites W2034938669 @default.
- W3150277572 cites W2047387695 @default.
- W3150277572 cites W2047726172 @default.
- W3150277572 cites W2058805092 @default.
- W3150277572 cites W2059205366 @default.
- W3150277572 cites W2069520354 @default.
- W3150277572 cites W2077486997 @default.
- W3150277572 cites W2107098622 @default.
- W3150277572 cites W2113043388 @default.
- W3150277572 cites W2114095008 @default.
- W3150277572 cites W2128713327 @default.
- W3150277572 cites W2131350133 @default.
- W3150277572 cites W2141947008 @default.
- W3150277572 cites W2146426024 @default.
- W3150277572 cites W2170120657 @default.
- W3150277572 cites W2337833922 @default.
- W3150277572 cites W2582719575 @default.
- W3150277572 cites W2606162141 @default.
- W3150277572 cites W2712701535 @default.
- W3150277572 cites W2800256972 @default.
- W3150277572 cites W2807377921 @default.
- W3150277572 cites W2891430988 @default.
- W3150277572 cites W2911842675 @default.
- W3150277572 cites W2935231655 @default.
- W3150277572 cites W2945332317 @default.
- W3150277572 cites W2958765021 @default.
- W3150277572 cites W2966241426 @default.
- W3150277572 cites W2997051047 @default.
- W3150277572 cites W2999568449 @default.
- W3150277572 cites W3005769489 @default.
- W3150277572 cites W3007915541 @default.
- W3150277572 cites W3010524097 @default.
- W3150277572 cites W3034998918 @default.
- W3150277572 cites W3078154952 @default.
- W3150277572 cites W3085761924 @default.
- W3150277572 cites W3094464202 @default.
- W3150277572 cites W3119394792 @default.
- W3150277572 cites W3126331913 @default.
- W3150277572 cites W3128862239 @default.
- W3150277572 cites W3155144050 @default.
- W3150277572 doi "https://doi.org/10.1002/macp.202100114" @default.
- W3150277572 hasPublicationYear "2021" @default.
- W3150277572 type Work @default.
- W3150277572 sameAs 3150277572 @default.
- W3150277572 citedByCount "2" @default.
- W3150277572 countsByYear W31502775722021 @default.
- W3150277572 countsByYear W31502775722023 @default.
- W3150277572 crossrefType "journal-article" @default.
- W3150277572 hasAuthorship W3150277572A5002985330 @default.
- W3150277572 hasAuthorship W3150277572A5010196373 @default.
- W3150277572 hasAuthorship W3150277572A5021184671 @default.
- W3150277572 hasAuthorship W3150277572A5025070309 @default.
- W3150277572 hasAuthorship W3150277572A5053474293 @default.
- W3150277572 hasAuthorship W3150277572A5056461337 @default.
- W3150277572 hasAuthorship W3150277572A5086039148 @default.
- W3150277572 hasBestOaLocation W31502775721 @default.
- W3150277572 hasConcept C11268172 @default.
- W3150277572 hasConcept C134121241 @default.
- W3150277572 hasConcept C15920480 @default.
- W3150277572 hasConcept C159985019 @default.
- W3150277572 hasConcept C178790620 @default.
- W3150277572 hasConcept C184651966 @default.
- W3150277572 hasConcept C185592680 @default.
- W3150277572 hasConcept C188027245 @default.
- W3150277572 hasConcept C192562407 @default.
- W3150277572 hasConcept C521977710 @default.
- W3150277572 hasConcept C67407626 @default.
- W3150277572 hasConceptScore W3150277572C11268172 @default.
- W3150277572 hasConceptScore W3150277572C134121241 @default.
- W3150277572 hasConceptScore W3150277572C15920480 @default.
- W3150277572 hasConceptScore W3150277572C159985019 @default.
- W3150277572 hasConceptScore W3150277572C178790620 @default.
- W3150277572 hasConceptScore W3150277572C184651966 @default.
- W3150277572 hasConceptScore W3150277572C185592680 @default.
- W3150277572 hasConceptScore W3150277572C188027245 @default.
- W3150277572 hasConceptScore W3150277572C192562407 @default.
- W3150277572 hasConceptScore W3150277572C521977710 @default.
- W3150277572 hasConceptScore W3150277572C67407626 @default.