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- W3150359172 abstract "Y. Zhao, C. Beuchat,Y. Domoto, J. Gajewy,A.Wilson, J.Mareda, N. Sakai, and S. Matile*, J. Am. Chem. Soc. 2014, 136, 2101. University of Geneva While cation-π interactions are widely recognized for providing stabilizing weak interactions, their anion-π counterparts have not received much attention. Herein, Matile and coworkers present conclusive experimental evidence for the importance of anion-π interactions in the catalytic Kemp elimination. The stabilizing effect on the anionic transition state of this reaction increases with the π-acidity of the catalysts, which are otherwise structurally similar. This insight could inspire the development of conceptually new catalysts with unprecedented activity." @default.
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- W3150359172 date "2013-09-18" @default.
- W3150359172 modified "2023-10-16" @default.
- W3150359172 title "Swiss Science Concentrates" @default.
- W3150359172 doi "https://doi.org/10.2533/chimia.2013.683" @default.
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