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• W3150402313 abstract "In the presence of Au/TiO2 (1 mol %), terminal alkynes react quantitatively with stoichiometric amounts of the unactivated digermane Me3Ge-GeMe3, forming exclusively cis-1,2-digermylated alkenes. We also establish the Au/TiO2-catalyzed hydrogermylation of terminal allenes with Et3GeH, which exhibits a highly regioselective mode of addition on the more substituted double bond forming vinylgermanes. Additionally, we provide preliminary results regarding the Pd nanoparticle-catalyzed C–C coupling of 1,2-digermyl alkenes with aryl iodides." @default.
• W3150402313 created "2021-04-13" @default.
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• W3150402313 date "2021-04-09" @default.
• W3150402313 modified "2023-10-16" @default.
• W3150402313 title "Synthesis of Vinylgermanes via the Au/TiO₂-Catalyzed <i>cis</i>-1,2-Digermylation of Alkynes and the Regioselective Hydrogermylation of Allenes" @default.
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• W3150402313 doi "https://doi.org/10.1021/acs.orglett.1c00997" @default.
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