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- W3150554095 abstract "Abstract Earth abundant metal catalysts hold advantages in cost, environmental burden and chemoselectivity over precious metal catalysts. Differences in reactivity for a given metal center result from ligand field strength, which can promote reaction through either open- or closed-shell carbon intermediates. Herein we report a simple protocol for cobalt-catalyzed alkene reduction. Instead of using an oxidative turnover mechanism that requires stoichiometric hydride, we find a reductive turnover mechanism that requires stoichiometric proton. The reaction mechanism appears to involve coordination and hydrocobaltation of terminal alkenes." @default.
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- W3150554095 date "2021-05-01" @default.
- W3150554095 modified "2023-10-03" @default.
- W3150554095 title "Cobalt-catalyzed alkene hydrogenation by reductive turnover" @default.
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- W3150554095 doi "https://doi.org/10.1016/j.tetlet.2021.153047" @default.
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