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• W3151086136 abstract "催化剂在 CeO2-ZrO2-La2O3 上支持了的 Pd (1.4 wt%) 的催化行为与不同 Ce/Zr 臼齿的比率混合了氧化物为甲醇分解被调查。氮吸附解吸附作用(赌注) ， X 光检查光电子光谱学(XPS ) ， H2 规划温度的减小(H2-TPR ) ， X 光检查衍射(XRD ) 和 Pd 分散分析被用于他们的描述。Pd/Ce0.76Zr0.18 La0.06O1.97 催化剂显示出最高的赌注表面区域，最好的 Pd 分散能力和最强壮的金属支持相互作用。而且， XPS 证明有格子缺点氧或活动的氧。根据 O 1s 大小的结果，格子缺点氧或活动的氧帮助处于一个部分氧化的状态维持 Pd 并且为甲醇分解增加了这项活动。Pd/Ce0.76Zr0.18La0.06O1.97 催化剂展出了最好的活动。甲醇的 100% 变换在约 260 ° C 被完成，它关于比另外的催化剂低的 20-40 ° C" @default.
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• W3151086136 date "2009-01-01" @default.
• W3151086136 modified "2023-09-24" @default.
• W3151086136 title "Catalytic methanol decomposition to carbon monoxide and hydrogen over Pd/CeO2-ZrO2-La2O3 with different Ce/Zr molar ratios" @default.
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