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- W3151159176 abstract "The montmorillonite hydrate with one HrO layer dehydroxylates or melts at 525 C and 5 + 1.4 kbar, conditions that are much lower than those found at lower pressures. Montmorillonite with basal spacing intermediate between two homogeneous states, which was interpreted as interstratification oftwo hydrates, is also stable at the elevated temperatures and pressures. Results confirm that the dehydration temperature of montmorillonite significantly increases with increasing HrO pressure, consistent with the idea that the density of interlayer HrO in montmorillonite is higher than that of pore HrO. Kinetic data show that the dehydration of interlayer HrO is fast (on the order of minutes) even at high HrO pressure, whereas the rehydration reaction is slower. The rehydration rate significantly increases when the sample cools to temperatures far below equilibrium. The preliminary experiments using micrograms of swelling clay, montmorillonite, affirm that synchrotron radiation can be a very useful tool to quantify the fluid-rock reactions occurring within a diamond-anvil cell." @default.
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- W3151159176 date "1994-01-01" @default.
- W3151159176 modified "2023-09-26" @default.
- W3151159176 title "Dehydration and hydration of montmorillonite at elevated temperatures and pressures monitored using synchrotron radiation" @default.
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