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- W3151300784 abstract "Flexible lithium-ion batteries (LIBs) are critical for the development of next-generation smart electronics. Conversion reaction-based electrodes have been considered promising to construct high energy–density flexible LIBs, which satisfy the ever-increasing demand for practical use. However, these electrodes suffer from inferior lithium-storage performance and structural instability during deformation and long-term lithiation/delithiation. These are caused by the sluggish reaction kinetics of active-materials and the superposition of responsive strains originating from the large lithiation-induced stress and applied stress. Here, we propose a stress-release strategy through elastic responses of nested wrinkle texturing of graphene, to achieve high deformability while maintaining structural integrity upon prolonged cycles within high-capacity electrodes. The wrinkles endow the electrode with a robust and flexible network for effective stress release. The resulting electrode shows large reversible stretchability, along with excellent electrochemical performance including high specific capacity, high-rate capability and long-term cycling stability. This strategy offers a new way to obtain high-performance flexible electrodes and can be extended to other energy-storage devices." @default.
- W3151300784 created "2021-04-13" @default.
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- W3151300784 date "2021-10-01" @default.
- W3151300784 modified "2023-10-16" @default.
- W3151300784 title "Stress release in high-capacity flexible lithium-ion batteries through nested wrinkle texturing of graphene" @default.
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- W3151300784 doi "https://doi.org/10.1016/j.jechem.2021.03.021" @default.
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